Sodium acetate (CH3COONa, also written NaOAc) is the sodium salt of acetic acid: a white, hygroscopic solid that dissolves readily in water. This product is the anhydrous powder. The crystal trihydrate and laboratory grades are listed separately: sodium acetate trihydrate, anhydrous AR, anhydrous LR and trihydrate AR.
Where it is used: sodium acetate with acetic acid makes the standard pH 4–6 buffer in laboratories; textile dye houses use it to neutralise sulfuric acid waste streams; tanneries use it as a pickling agent in chrome tanning; food plants use it for pH control and shelf life. The trihydrate melts at about 58 °C and is the salt inside reusable heat packs. For dye levelling, see Glauber's salt.
| Formula | CH3COONa (C2H3NaO2) |
| Molar mass | 82.03 g/mol (anhydrous); 136.08 g/mol (trihydrate) |
| CAS number | 127-09-3 (anhydrous); 6131-90-4 (trihydrate) |
| Form supplied | White powder or granules, anhydrous |
| Other names | NaOAc, sodium ethanoate, acetic acid sodium salt |
What is CH3COONa?
CH3COONa is the formula of sodium acetate, the salt formed when acetic acid is neutralised with sodium hydroxide.
Is sodium acetate acidic or basic?
It is the salt of a weak acid and a strong base, so its water solution is mildly alkaline. Mixed with acetic acid it forms a buffer that holds pH between about 4 and 6.
Anhydrous or trihydrate: which should I buy?
Both give the same acetate. The trihydrate carries three molecules of water, so you need about 1.66 kg of trihydrate to replace 1 kg of anhydrous. Choose anhydrous for dry blends and to save freight; choose trihydrate for heat packs or where a method specifies it.