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| Product Name | GLUTARALDEHYDE |
| Part Number | RXSOL-19-1196-025 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
| Phone | +91 22 65113333 / 5555 / 9999 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| 123@rxmarine.com | |
| Website | www.rxmarine.com |
| Name of Substance | Cas Number | EC Number | Wight % |
| Glutaraldehyde | 111-30-8 | 203-856-5 | 50% |
| Non Hazardous Ingirdent | 50 % |
| Signal Word | Danger |
| Hazard Statements |
H302 + H332 Harmful if swallowed or if inhaled. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects. EUH071 Corrosive to the respiratory tract |
| Precautionary statements - prevention |
P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. |
| Precautionary statements - response |
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P310 IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician. |
| Eye Contact | Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately. |
| Skin Contact | In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. |
| Inhalation: | Move to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately if symptoms occur. |
| Ingestion: | Do not induce vomiting. Obtain medical attention.If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. |
| Notes to Physician | Treat symptomatically |
| Flammability | Non-flammable. |
| Flash Point | Not applicable. |
| Suitable extinguishing media | No information available |
|
Hazardous combustion products |
When heated to decomposition, it emits acrid smoke and fumes. |
| Protective Equipment | Use personal protective equipment. |
| Specific Hazards Arising from the Chemical | Not considered to be a significant fire risk. |
| Small Spillage | Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements |
| Personal Protection | Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. |
| Enviromental Precaution | Do not let product enter drains. |
|
Methods and materials for containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts |
| Handling | Do not ingest. Do not breathe dust. Avoid contact with eyes. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing agents, acids. |
| Storage | Light Sensitive. Refrigerate. Store in light-resistant containers. Keep containers tightly closed. Keep containers in a cool, wellventilated area.Packing : Only packagings which are approved (e.g. acc. to ADR) may be used. |
| Advice on general occupational hygiene | Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
| Engineering Control | Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. |
| Personal Protection |
Eye/face Protection : Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin and body protection : Wear appropriate protective gloves and clothing to prevent skin exposure. Respiratory Protection : Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator exposure limits are exceeded or if irritation or other symptoms are experienced. |
| Other Protection Measure | Handle in accordance with good industrial hygiene and safety practice. |
| Exposure Limit | Glutaraldehyde TWA: 0.2 (ppm) [Australia] TWA: 0.82 (mg/m3) [Australia] TWA: 0.25 CEIL: 0.2 (ppm) from NIOSH CEIL: 0.2 (ppm) from OSHA (PEL) [United States] TWA: 0.05 STEL: 0.05 (ppm) [United Kingdom (UK)] Consult local authorities for acceptable exposure limits. |
Gloves Suit
| Form | Liquid |
| Colour | Clear |
| Odour | Pungent |
| Odor Threshold | No Information Available |
| pH | 3.5 - 4.5 |
| Freezing Point | -13 °C |
| Boiling Point | 101°C |
| Flash Point | Not Applicable |
| Evaporation Rate | Not Applicable |
| Flammability (solid, gas) | No Data Available |
| Explosive limits | No Data Available |
| Vapour pressure | 21 hPa at 20 °C |
| Vapour Density | 0.8 |
| Relative density Information | 1.10 at 25 °C |
| Partition coefficient | No data available |
| Explosive properties | None |
| Solubility | Soluble in water |
| Ignition temperature | 275 °C |
| Recativity | Forms explosive mixtures with air on intense heating. |
| Stability | Product is stable. |
| Possibility of hazardous reactions |
Violent reactions possible with:Amines, Strong oxidizing agents Violent polymerisation may be caused by: Strong bases, Strong acids |
| Conditions to avoid | Strong Heating |
| Incompatible materials | Aluminium, various metals, Mild steel |
| Hazardous Polymerization | Hazardous polymerization does not occur. |
| Rout Of Entry | Absorbed through skin. Eye contact. Inhalation. Ingestion. |
| Toxicity to Animal | WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 100 mg/kg [Mouse]. Acute dermal toxicity (LD50): >2500 mg/kg [Rat]. Acute toxicity of the vapor (LC50): 480 mg/m 4 hours [Rat]. 3 |
| Toxic Effects on Humans |
CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for human or animal.) by ACGIH [Glutaraldehyde]. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. [Glutaraldehyde]. Mutagenic for bacteria and/or yeast. [Glutaraldehyde]. DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Reproductive system/toxin/male [SUSPECTED] [Glutaraldehyde]. Contains material which may cause damage to the following organs: blood, the reproductive system, liver, mucous membranes, spleen, central nervous system (CNS), Urinary system. |
| Special Remarks on other Toxic Effects on Humans: |
Potential Health Effects: Eye: Causes severe eye irritation. May cause eye injury or chemical conjunctivitis. Skin: Causes moderate to severe skin irritation. It may be absorbed through the skin, although poorly. May cause allergic contact dermatitis with itching and skin rash. May cause staining of the skin and nails to a brown or golden brown color. Ingestion: Harmful if swallowed. May cause severe irritation of the digestive tract with burning sensation in the chest, abdominal pain, cramping, vomiting, diarrhea (perhaps bloody diarrhea), vascular collapse, and coma. May also affect liver (increased liver enzymes, liver damage), spleen, blood (normocytic anemia), metabolism (weight loss), behavior (somnolence, excitement, dizziness, lethargy, ataxia, seizures), metabolism (weight loss), urinary system ( abnormal reneal function, anuria) Inhalation: Harmful if inhaled. Can cause respiratory tract irritation and sudden headaches. |
| Eco Toxicity | Not Available |
| COD and BOD 5 | Not Available |
| Products of Biodegradation: | No Information available |
| Mobility in soil | No Information available |
| Results of PBT and vPvB assessment | Substance(s) in the mixture do(es) not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII, or a PBT/vPvB assessment was not conducted.. |
| Other adverse effects | Discharge into the environment must be avoided. |
| Waste treatment Method | Waste material must be disposed of in accordance with the national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself |
DOT
| UN Number | UN1307 |
| Proper shipping name |
CORROSIVE LIQUID, N.O.S. (GLUTARDIALDEHYDE SOLUTION) |
| Hazard Class | 8 |
| Packing group | II |
TDG
| UN Number | UN1307 |
| Proper shipping name |
CORROSIVE LIQUID, N.O.S. (GLUTARDIALDEHYDE SOLUTION) |
| Hazard Class | 8 |
| Packing group | II |
IATA
| UN Number | UN1307 |
| Proper shipping name |
CORROSIVE LIQUID, N.O.S. (GLUTARDIALDEHYDE SOLUTION) |
| Hazard Class | 8 |
| Packing group | II |
IMDG/IMO
| UN Number | UN1307 |
| Proper shipping name |
CORROSIVE LIQUID, N.O.S. (GLUTARDIALDEHYDE SOLUTION) |
| Hazard Class | 8 |
| Packing group | II |
| Fedral and State Regulation | Pennsylvania RTK: Glutaraldehyde Florida: Glutaraldehyde Massachusetts RTK: Glutaraldehyde New Jersey: Glutaraldehyde California Director's list of Hazardous Substances: Glutaraldehyde TSCA 8(b) inventory: Glutaraldehyde; Water TSCA 8(a) PAIR: Glutaraldehyde TSCA 8(d) H and S data reporting: Glutaraldehyde: 9/30/91 to 9/30/01 |
| Other Regulation | OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances. |
| WHMIS (Canada) | CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS D-2B: Material causing other toxic effects (TOXIC). CLASS E: Corrosive liquid. |
| DSCL (EEC) | R36- Irritating to eyes. S2- Keep out of the reach of children. S24/25- Avoid contact with skin and eyes. S46- If swallowed, seek medical advice immediately and show this container or label. |
| HMIS | |
| Health Hazard | : 2 |
| Fire Hazard | : 0 |
| Reactivity | : 0 |
| Personal Protection | : H |
| Fire : | |
| Health Hazard | : 2 |
| Fire Hazard | : 0 |
| Reactivity | : 0 |
| Specific Hazard | : H |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. |