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Silica Gel Blue
Product MSDS:

Porduct Name               Silica Gel Blue
Part Number   RXSOL-19-1998-025

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA  

Phone +91 22 20871200 - 1400
Fax +91 22 27612100 :::AOH :0091 9821214367
Email mail@rxmarine.com
Website www.rxmraine.com

Chemical Name                 Cas No                        EC No              Whight                          Formula                   
  Silica Gel Blue        112926-00-8 231-545-4 - -
Signal Word  Danger
Hazard Statements H300 + H310 Fatal if swallowed or in contact with skin.
Precautionary statements   P262 Do not get in eyes, on skin, or on clothing. P280 Wear protective gloves/ protective clothing. P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P302 + P352 + P310 IF ON SKIN: Wash with plenty of water. Immediately call a POISON CENTER/ doctor.
Classification of the substance or mixture Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008.
Supplemental Hazard      Statements None
Other hazards  This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

General advice Consult a physician. Show this material safety data sheet to the doctor in attendance.
If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. 
Eye Contact  Flush eyes with water as a precaution. 
Swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. 
Skin Contact   Wash off with soap and plenty of water. 
Inhalation Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary. 
Ingestion Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Most important symptoms and effects, both acute and delaye The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
Indication of any immediate medical attention and special treatment needed  No data available

Flammability                                                  May be combustible at high temperature.
Suitable extinguishing media  Dry powder Dry sand
Unsuitable extinguishing media Do NOT use water jet.
Special hazards arising from the substance or mixture  Carbon oxides Nitrogen oxides (NOx) Combustible.
Further information Use water spray to cool unopened containers.
Hazardous combustion
products
Fire may cause the evolution of Sulphur oxides, nitrogen oxides.
Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary.
Protective Equipment Use personal protective equipment.
Specific Hazards Arising from the Chemical Has a fire-promoting effect due to the release of oxygen.
Ambient fire may liberate hazardous vapours.

Personal precautions, protective equipment and emergency procedures Avoid dust formation. Avoid breathing vapours, mist or gas. For personal protection see section 8.
Spillage Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal.
Personal Protection Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8.
Enviromental Precaution Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Methods and materials for
containment and cleaning
Sweep up and shovel. Keep in suitable, closed containers for disposal. 
Reference to other sections    For disposal see section 13.

Advice on protection against fire and explosion Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge.
Incompatible materials  Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. 
Hygiene measures Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. For precautions see section 2.2.
Advice on safe handling Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.
Conditions for safe storage, including any incompatibilities  Store in cool place. Keep container tightly closed in a dry and well-ventilated place. 
Storage conditions Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store in cool place.
Storage class Storage class (TRGS 510): 3: Flammable liquids
Specific end use(s) A part from the uses mentioned in section 1.2 no other specific uses are stipulated 
Advice on general occupational hygiene Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance.

Exposure controls  No specific additional engineering controls are required. Provide good natural or artificial ventilation. 
Engineering Control Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Body Protection Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Respiratory protection
Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Other Protection  Measure Handle in accordance with good industrial hygiene and safety practice.
Control of    environmental exposure No special environmental precautions required. 

APPEARANCE Granules or beads.
COLOUR Blue
ODOUR Odourless
SOLUBILITY Not soluble in water.
DECOMPOSITION TEMPERATURE (°C) >1600
 

Reactivity                        No data available
Chemical stability Stable under recommended storage conditions. 
Possibility of hazardous reactions No data available
Conditions to avoid Heat, flames and sparks.                                                                                         
Incompatible materials
Strong oxidizing agents 
Hazardous decomposition products Other decomposition products - no data available In the event of fire: see section 5

Acute toxicity  No data available                 
Skin corrosion/irritation No data available
Serious eye      damage/irritation No data available
Respiratory or skin    sensitization  No data available
Carcinogenicity No data available
Germ cell  mutagenicity  No data available
Reproductive toxicity  No data available
Specific target organ toxicity - single      exposure
No data available
Additional Information RTECS: UF9625000 Lung irritation, Cyanosis, Central nervous system depression To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Persistence and degradability No data available
Toxicity to fish  Static test LC50 - Oncorhynchus mykiss (rainbow trout) - 75 mg/l - 96 h (OECD Test Guideline 203)
Toxicity to daphnia and other aquatic invertebrates Static test EC50 - Daphnia magna (Water flea) - 42,81 mg/l - 48 h (OECD Test Guideline 202) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: maleic acid
Toxicity Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 1.520 mg/l - 96 h
Toxicity to bacteria  EC10 - Bacteria - 14 mg/l - 72 h Remarks: (Lit.) EC5 - E.coli - 15.000 mg/l Remarks: (Lit.) (maximum permissible toxic concentration)
Toxicity to algae Static test ErC50 - Pseudokirchneriella subcapitata (green algae) - 74,35 mg/l - 72 h (OECD Test Guideline 201) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: maleic acid
Products Biodegradation The methods for determining the biological degradability are not applicable to inorganic substances.
Mobility in soil No data available
Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting       properties No data available
Other adverse effects No data available .

Product Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging Dispose of as unused product.
Waste treatment      Method See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

UN number ADR/RID:                         IMDG:                                IATA: 
UN proper shipping name  ADR/RID:                         IMDG:                                 IATA:
Transport hazard class(es)      ADR/RID:                         IMDG:                                 IATA: 
Packaging group ADR/RID:                         IMDG:                                 IATA:
Environmental hazards ADR/RID: No                    IMDG: No                           IATA: No
Special precautions for user No data available
Further information Not classified as dangerous in the meaning of transport regulations.

Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
Other regulations Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment For this product a chemical safety assessment was not carried out

Other Information

The information above is believed to be accurate and represents the  best information   currently    available  to us.  However,   we   make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and  weassume  no liability resulting from its use. Users should make  their  own  investigations  to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International  has been advised of the possibility of such damages.