If RXH is not acid enough to release a proton at alkaline pH, as it is the case with amines, then the reaction has to be carried out in two steps. During the first step the first EO mole is added at acid pH, so that the amine is transformed in ammonium. The reaction produce the mono-, di- and tri-ethanol amines.
Proton release from ammonium NH4+ → NH3 + H+ (here RX- is NH3) Then, the three condensation reactions:
NH3 + EO → NH2CH2CH2OH (mono-ethanol amine MEA)
NH2CH2CH2OH + EO → NH(CH2CH2OH)2 (di-ethanol amine DEA)
NH-(CH2CH2OH)2 + EO → N(CH2CH2OH)3 (tri-ethanol amine TEA)
With an alkyl amine, first the alkyl ammoniumion is formed and it is deprotonated:
RNH3+ → RNH2 + H+ (here RX- is RNH2)
RNH2 + EO → RNH-CH2CH2OH (mono-ethanol alkyl amine)
RNH-CH2CH2OH + EO → RN(CH2CH2OH)2 (di-ethanol alkyl amine)
Once the ethanol amine is attained, the EO polycondensation is carried out at alkaline pH as previously. In many instance the first ethoxylation is stopped when the monoethanol alkyl amine is formed in order to avoid the polycondensation in more than one chain.
PRODUCT NAME | : | TRI ETHANOL AMINE |
CAS number | : | 102-71-6 |
UN number | : | |
Formula | : | (HOC2H4)3N |
Odour | : | SLIGHTLY AMMONIACAL |
Solubility in water | : | COMPLETE |
Density | : | 1.13 at 20 oC |
Boiling point | : | 360 oC |
Melting point | : | 21 oC |
Viscosity | : | |
Flashpoint | : | 190 oC |
Explosive limits | : | 1.2 - ? Vol% |
Vapour pressure | : | .03 mbar at 20 oC |
Skin absorption/irritation | : | YES |
TLV Country NL Year 1995 | : | |
Pollution category 1994 | : |
D |
TEA
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On exposure to air it gradually absorbs oxygen and darkens in color and develops a more pronounced odour. It decomposes when heated at 80 to 100 °C.
An unsaturated fatty acid that is the most widely distributed and abundant fatty acid in nature. it is used commercially in the preparation of oleates and lotions, and as a pharmaceutical solvent. Major constit. of plant oils e.g. olive oil (ca. 80%), almond oil (ca. 80%) and many others, mainly as glyceride. Constit. of tall oil.
Also present in apple, melon, raspberry oil, tomato, banana, roasted peanuts, black tea, rice bran, cardamon, plum brandy, peated malt, dairy products and various animal fats. Component of citrus fruit coatings. Emulsifying agent in foods Oleic acid is a monounsaturated omega-9 fatty acid found in various animal and vegetable fats. The trans isomer of oleic acid is called elaidic acid.
OLEICACID 90 KG PACK
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Sodium Metasilicate is incompatible with acids, bronze, aluminum, brass, copper, lead, tin, zinc and other alkali sensitive metals.
Physical and Chemical Properties
Sodium metasilicates are white, free-flowing, granular products that feel slippery to the touch when wet. These products do not have a distinguishing odor. Sodium metasilicates are stable at normal temperatures and pressures and are not combustible. Spills of sodium metasilicate can be very slippery when wet.
Sodium metaSilicate
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We also keeping other grades of Phosphate Chemicals and Formate Chemicals. Our product range covers high-quality products and most competitive price,
(1)phosphate chemicals:
Red phosphorus
Malic acid
Phosphoric Acid 75%,85% food grade
Polyphosphoric Acid 105%,115%
Phosphorus acid 98.5%,99%
Sodium Acid Pyrophosphate
Sodium Hexameta Phosphate
Sodium Tripoly Phosphate
Trisodium Phosphate
Tetra-sodium Pyrophosphate
Monoammonium Phosphate
Diammonium Phosphate
Monopotassium Phosphate
Phosphorus pentoxide
Phosphorus trichloride
Glyphosate
Ferro Phosphorus
(2)formate chemicals:
Sodium Hexameta Phosphate SHMP, SHMP or Metaphos , Water Softner
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